Mesoporous 2D covalent organic frameworks based on shape-persistent arylene-ethynylene macrocycles
نویسندگان
چکیده
منابع مشابه
Mesoporous 2D covalent organic frameworks based on shape-persistent arylene-ethynylene macrocycles† †Electronic supplementary information (ESI) available: Experimental procedures, TGA, FT-IR, PXRD and NMR spectra of compounds. See DOI: 10.1039/c5sc00894h
Macrocycle-to-framework strategy was explored to prepare covalent organic frameworks (COFs) using shape-persistent macrocycles as multitopic building blocks. We demonstrate well-ordered mesoporous 2D COFs (AEM–COF-1 and AEM–COF-2) can be constructed from tritopic arylene-ethynylene macrocycles, which determine the topology and modulate the porosity of the materials. According to PXRD analysis a...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c5sc00894h